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Document ID ca-gcdwqgtd-2008-01-07-8 Title Guidelines for Canadian Drinking Water Quality: Guideline Technical Document – Arsenic URL https://www.canada.ca/en/health-canada/services/publications/healthy-living/guidelines-canadian-drinking-water-quality-guideline-technical-document-arsenic/page-8-guidelines-canadian-drinking-water-quality-guideline-technical-document-arsenic.html Jurisdiction /ca Subdomain(s) Drinking water, Water treatment processes Language en Status completed Analyzed at 2026-03-17 15:46:08.450492+00:00 Relevance Authoritative technical guidance on arsenic removal for drinking water systems.

Q Qualitative Requirements (15)

Req ID Category Intent Legal Status Name Subdomain(s) Context Conditions Confidence
#Q001treatmenttreatmentrecommendedDetermination of pretreatment needsdrinking waterIt is important to determine what, if any, pretreatment is required.high
#Q002monitoringoperationalguidanceArsenic speciation assessmentdrinking waterSpeciation may be performed to assess the species of arsenic present; however, there appears to be limited benefit with respect to time and costs involved.high
#Q003treatmentoperationalrecommendedLime softening restrictiondrinking waterHowever, lime softening is an expensive process and is not recommended unless there is also a need to reduce hardness in the raw water feed (U.S. EPA, 2000).Unless there is also a need to reduce hardness in the raw water feedhigh
#Q004treatmentoperationalrecommendedIon exchange applicationdrinking waterThese systems are recommended for water supplies with low concentrations of total dissolved solids and sulphate (U.S. EPA, 2000).For water supplies with low concentrations of total dissolved solids and sulphatehigh
#Q005monitoringoperationalrecommendedResidential treatment device monitoringdrinking waterPeriodic testing by an accredited laboratory should be conducted on both the water entering a treatment device and the water it produces to verify that the device is effective.high
#Q006monitoringoperationalrecommendedPre-installation well water testingdrinking waterBefore a treatment device is installed, the well water should be tested to determine general water chemistry and to verify the concentration of arsenic.Before a treatment device is installedhigh
#Q007monitoringoperationalrecommendedTesting for competing ions and organic matterdrinking waterThe testing should also include assessing the presence and concentration of competing ions (e.g., fluoride, iron, sulphate, silicate) and organic matter in the water, which could interfere with arsenic removal.high
#Q008treatmenttreatmentrecommendedPretreatment oxidation step for residential systemsdrinking waterGiven that most technology cannot effectively remove trivalent arsenic, pretreatment with an oxidation step is recommended to convert trivalent (dissolved) arsenic to pentavalent (filterable) arsenic, to ensure good removal by the treatment device (U.S. EPA, 2001a).high
#Q009operationaloperationalrecommendedReview of manufacturer claimsdrinking waterIndividuals should refer to the manufacturer's claims in its literature to obtain information on the amount of arsenic that the treatment device will remove, as well as operational and maintenance requirements.high
#Q010treatmentoperationalguidanceInfluent water pretreatment for membrane protectiondrinking waterA consumer may need to pretreat the influent water to reduce fouling and extend the service life of the membrane.When using reverse osmosis systemshigh
#Q011operationalhealthrecommendedDietary compensation for mineral removaldrinking waterSince beneficial minerals such as calcium and magnesium are removed by both distillation and reverse osmosis processes, it is important to consume a reasonably well-balanced diet to offset the removal of these minerals.When using distillation or reverse osmosis processeshigh
#Q012treatmenthealthrecommendedUse of certified treatment devicesdrinking waterHealth Canada does not recommend specific brands of treatment devices, but it strongly recommends that consumers use devices that have been certified by an accredited certification body as meeting the appropriate NSF International (NSF)/American National Standards Institute (ANSI) drinking water treatment unit standards.high
#Q013administrativereportingmandatoryAccreditation of certification organizationsdrinking waterCertification organizations provide assurance that a product conforms to applicable standards and must be accredited by the Standards Council of Canada (SCC).high
#Q014monitoringoperationalrecommendedFinished water testing to verify treatment efficacydrinking waterIt is important to determine what, if any, pretreatment is required and to have the finished water tested by an accredited laboratory to ensure that any designed system is attaining the desired arsenic removal.high
#Q015operationaloperationalmandatoryDisposal of treatment residualsdrinking waterThese systems also create significant quantities of either sludge or brine, which must be disposed of appropriately, thus increasing the cost of these processes (NDWAC, 2001).Applicable to municipal-scale arsenic treatment technologieshigh

P Quantitative Requirements (17)

Req ID Category Intent Legal Status Name Subdomain(s) Limit Type Limit Value Context Conditions Confidence
#P001chemicaltreatmentmandatoryArsenic (NSF/ANSI Certification Final Concentration)drinking waterrequirement< 0.010 mg/LCertification to the standard verifies only that a final concentration of less than 0.010 mg/L is achieved.Applies to residential drinking water treatment devices certified to NSF/ANSI standards.high
#P002chemicaltreatmentmandatoryArsenic (NSF/ANSI Standards 53, 58, 62 Influent Challenge)drinking waterrequirement0.3 mg/LThe device will have to be able to reduce the concentration of arsenic in water from 0.3 to 0.010 mg/L.For a drinking water treatment device to be certified to NSF/ANSI Standards 53, 58, or 62 (high concentrations).high
#P003chemicaltreatmentguidanceArsenic (NSF/ANSI Standards Low Influent Challenge)drinking waterrequirement< 0.05 mg/LDevices certified as reducing the concentration of arsenic from 0.05 to 0.010 mg/L are intended for treating water with lower initial concentrations (i.e., less than 0.05 mg/L) of arsenic.Intended for treating water with lower initial concentrations of arsenic.high
#P004physicaltreatmentguidanceArsenic Speciation pH Rangedrinking waterOG4-10 pHIn water in the pH range of 4-10, the predominant As(III) species are neutral in charge, while As(V) species are negatively charged.Relevant for assessing removal efficiency of As(III) vs As(V).high
#P005chemicaltreatmentguidanceCoagulation/Filtration Finished Water Arsenic Concentrationdrinking watertreatment_goal0.003-0.005 mg/Lwhen coagulation/filtration is combined with pretreatment (oxidation to convert arsenic to its pentavalent form) and a polishing step (polishing the finished water with ion exchange)Total arsenic levels in finished drinking water.high
#P006chemicaltreatmentguidanceLime Softening Finished Water Arsenic Concentrationdrinking watertreatment_goal0.001-0.003 mg/LLime softening is widely used in large utilities and is effective at reducing total arsenic in drinking waterTypically used when there is also a need to reduce hardness.high
#P007chemicaltreatmentguidanceActivated Alumina Effluent Arsenic Leveldrinking watertreatment_goal< 0.01 mg/LPilot plant studies of arsenic removal using activated alumina achieved effluent arsenic levels of <0.01 mg/LSimms and Azizian, 1997 study.high
#P008designtreatmentguidelineActivated Alumina Removal Efficiencydrinking watertreatment_goal95 %The U.S. EPA has identified activated alumina as a best available technology for arsenic removal, with a removal efficiency of 95%U.S. EPA, 2001a reference.high
#P009chemicaltreatmentguidanceIon Exchange Finished Water Arsenic Concentrationdrinking watertreatment_goal0.003 mg/LIon exchange processes in combination with an oxidation pretreatment step have been shown to reduce total arsenic in finished drinking water to levels as low as 0.003 mg/L.Recommended for water supplies with low TDS and sulphate.high
#P010designtreatmentguidanceReverse Osmosis Municipal Removal Efficiencydrinking watertreatment_goal85 %Reverse osmosis systems, when combined with a pretreatment step, can remove up to 85% of total arsenic from drinking water.May not be suitable where water resources are scarce due to brine rejection.high
#P011chemicaltreatmentguidanceIron Oxide-Coated Sand Adsorption Effluentdrinking watertreatment_goal< 0.005 mg/Liron oxide-coated sand and granular ferric hydroxide can remove As(III) and As(V) present in the water to a concentration below 0.005 mg/LApplicable to small water treatment utilities.high
#P012chemicaltreatmentguidelineResidential Treatment Device Arsenic Concentrationdrinking watertreatment_goal< 0.010 mg/LResidential treatment devices are affordable and can remove arsenic from drinking water to concentrations below 0.010 mg/L.Private residential drinking water treatment device.high
#P013designtreatmentguidanceResidential Reverse Osmosis Mineral Removal Efficiencydrinking waterrequirement98 %can remove up to 98% of other dissolved minerals as well as fine colloidal and coarse suspended matterMajor advantage of reverse osmosis systems.high
#P014chemicaltreatmentguidanceProfessionally Designed Residential System Effluentdrinking watertreatment_goal< 0.005 mg/LA qualified professional can design a system to meet residential needs and achieve arsenic concentrations below 0.005 mg/L.For example, a system designed with two or more filters in series.high
#P015designtreatmentguidanceMunicipal Scale Technology General Removal Efficiencydrinking watertreatment_goal> 90 %Removal efficiency can be very good (>90%) for technologies including coagulation/filtration, lime softening, activated alumina, ion exchange, and reverse osmosis.high
#P016chemicaltreatmentguidanceIon Exchange Laboratory Column Study Effluentdrinking watertreatment_goal0.002 mg/LLaboratory column studies using ion exchange resin achieved effluent concentrations as low as 0.002 mg/L where the influent had an arsenic concentration of 0.021 mg/L.Influent concentration of 0.021 mg/Lhigh
#P017chemicaltreatmentguidanceIon Exchange Laboratory Column Study Influent Concentrationdrinking waterrequirement0.021 mg/LLaboratory column studies using ion exchange resin achieved effluent concentrations as low as 0.002 mg/L where the influent had an arsenic concentration of 0.021 mg/L.high

D Definitions (14)

Req ID Category Name Context Confidence
#D001treatment deviceprivate residential drinking water treatment devicehigh
#D002point of useat the faucetmedium
#D003point of entrywhere water enters the homemedium
#D004NSFNSF Internationalhigh
#D005ANSIAmerican National Standards Institutehigh
#D006SCCStandards Council of Canadahigh
#D007water blendingcombining water from a source that has high levels of arsenic with one that has a much lower concentration of arsenichigh
#D008influentincominghigh
#D009rejectwastehigh
#D010trivalent arsenicdissolved arsenichigh
#D011pentavalent arsenicfilterable arsenichigh
#D012NSF/ANSI Standard 53Drinking Water Treatment Units -- Health Effectshigh
#D013NSF/ANSI Standard 58Reverse Osmosis Drinking Water Treatment Systemshigh
#D014NSF/ANSI Standard 62Drinking Water Distillation Systemshigh